Category Archives: Engineering

Sewage jokes, limericks, and a song.

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I ran for water commissioner (sewer commissioner) of Oakland county, Michigan last year, lost, but enjoyed my run. It’s a post that has a certain amount of humor built-in. If you can’t joke about yourself, you’ve got no place in the sewer. So here are some sewage jokes, and poems, beginning with an old favorite; one I used often in my campaign:3b37b9cab2d27693de2aa7004a3d90ef

Why was Piglet staring into the toilet?
He was looking for Poo.

Last week someone broke into the police station and stole all the toilets. The cops are still searching. So far, they have nothing to go on.paperwork

On administration: In life as on the toilet, the job isn’t done until the paperwork is finished.

Speaking of toilet paper: do you know why Star Trek is like toilet paper? They both go past Uranus and capture Klingons. I wrote an essay on Toilet paper — really. 

Here’s my campaign song and video. It’s sung by Art Carney (I’ve no rights, but figure they’ve expired). The pictures are of me, my daughter, and various people we met visiting sewage treatment plants around the county. Great men and a few great women who don’t mind getting their hands dirty. 

septic12

The Turd Burglar, We’re No.1 in the No. 2 business. What a motto!

And now for sewage Limericks:

There once was a man named McBride.
Who fell in the sewer and died.
The same day his brother
Fell in another,
And they were interred side by side.

There is a double intent in that Limerick, in case you missed it

By the sewer she lived, by the sewer she died. Some said t’was disease, but I say, Suicide

sewage treatment

sewage treatment plant in Pontiac, MI — the county’s largest.

How do you describe a jocular sewage joker? pun gent.

Life is like a sewer, what you get out of it is what you put into it (Tom Lehrer). And sometimes it stinks.

Robert E. Buxbaum, June 4, 2017. There is just one more sewage joke I know, but I thought I’d leave it out. It concerns the sewage backup at the prom. Unfortunately, the punchline stinks.

A clever, sorption-based, hydrogen compressor

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Hydrogen-powered fuel cells provide weight and cost advantages over batteries, important e.g. for drones and extended range vehicles, but they require highly compressed hydrogen and it’s often a challenge compressing the hydrogen. A large-scale solution I like is pneumatic compression, e.g. this compressor. One would combine it with a membrane reactor hydrogen generator, to fill tanks for fuel cells. The problem is that this pump is somewhat complex, and would likely add air impurities to the hydrogen. I’d now like to describe a different, very clever hydrogen pump, one that suited to smaller outputs, but adds no impurities and and provides very high pressure. It operates by metallic hydride sorption at low temperature, followed by desorption at high temperature.

Hydride sorption -desorption pressures vs temperature.

Hydride sorption -desorption pressures vs temperature, from Dhinesh et al.

The metal hydriding reaction is M + nH2 <–> MH2n. Where M is a metal or metallic alloy and MH2n is the hydride. While most metals will undergo this reaction at some appropriate temperature and pressure, the materials of practical interest are exothermic hydrides that is hydrides that give off heat on hydriding. They also must undergo a nearly stoichiometric absorption or desorption reaction at reasonable temperatures and pressures. The plot at right presents the plateau pressure for hydrogen absorption/ desorption in several, exothermic metal hydrides. The most attractive of these are shown in the red box near the center. These sorb or desorb between 1 and 10 atmospheres and 25 and 100 °C.

In this plot, the slope of the sorption line is proportional to the heat of sorption. The most attractive materials for this pump are the ones in the box (or near) with a high slope to the line implying a high heat of sorption. A high heat of sorption means you can get very high compression without too much of a temperature swing.

To me, NaAlH4 appears to be the best of the materials. Though I have not built a pump yet with this material, I’d like to. It certainly serves as a good example for how the pump might work. The basic reaction is:

NaAl + 2H2 <–> NaAlH4

suggesting that each mol of NaAl material (50g) will absorb 2 mols of hydrogen (44.8 std liters). The sorption line for this reaction crosses the 1 atm horizontal line at about 30°C. This suggests that sorption will occur at 1 am and normal room temperature: 20-25°C. Assume the pump contains 100 g of NaAl (2.0 mols). Under ideal conditions, these 100g will 4 mols of hydrogen gas, about 90 liters. If this material in now heated to 226°C, it will desorb the hydrogen (more like 80%, 72 liters) at a pressure in excess of 100 atm, or 1500 psi. The pressure line extends beyond the graph, but the sense is that one could pressure in the neighborhood of 5000 psi or more: enough to use filling the high pressure tank of a hydrogen-based, fuel cell car.

The problem with this pump for larger volume H2 users is time. It will take 2-3 hours to cycle the sober, that is, to absorb hydrogen at low pressure, to heat the material to 226°C, to desorb the H2 and cycle back to low temperature. At a pump rate of 72 liters in 2-3 hours, this will not be an effective pump for a fuel-cell car. The output, 72 liters is only enough to generate 0.12kWh, perhaps enough for the tank of a fuel cell drone, or for augmenting the mpg of gasoline automobiles. If one is interested in these materials, my company, REB Research will be happy to manufacture some in research quantities (the prices blow are for materials cost, only I will charge significantly more for the manufactured product, and more yet if you want a heater/cooler system).

Properties of Metal Hydride materials; Dhanesh Chandra,* Wen-Ming Chien and Anjali Talekar, Material Matters, Volume 6 Article 2

Properties of Metal Hydride materials; Dhanesh Chandra,* Wen-Ming Chien and Anjali Talekar, Material Matters, Volume 6 Article 2

One could increase the output of a pump by using more sorbent, perhaps 10 kg distributed over 100 cells. With this much sorbent, you’ll pump 100 times faster, enough to take the output of a fairly large hydrogen generator, like this one from REB. I’m not sure you get economies of scale, though. With a mechanical pump, or the pneumatical pump,  you get an economy of scale: typically it costs 3 times as much for each 10 times increase in output. For the hydride pump, a ten times increase might cost 7-8 times as much. For this reason, the sorption pump lends itself to low volume applications. At high volume, you’re going to want a mechanical pump, perhaps with a getter to remove small amounts of air impurities.

Materials with sorption lines near the middle of the graph above are suited for long-term hydrogen storage. Uranium hydride is popular in the nuclear industry, though I have also provided Pd-coated niobium for this purpose. Materials whose graph appear at the far, lower left, titanium TiH2, can be used for permanent hydrogen removal (gettering). I have sold Pd-niobium screws for this application, and will be happy to provide other shapes and other materials, e.g. for reversible vacuum pumping from a fusion reactor.

Robert Buxbaum, May 26, 2017 (updated Apr. 4, 2022). 

Future airplane catapults may not be electric

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President Trump got into Hot Water with the Navy this week for his suggestion that they should go “back to god-damn steam” for their airplane catapults as a cure for cost over-runs and delays with the Navy’s aircraft carriers. The Navy had chosen to go to a more modern catapult called EMALS (electromagnetic, aircraft launch system) based on a traveling coil and electromagnetic pulses. This EMAL system has cost $5 Billion in cost over-runs, has added 3 years to the program, and still doesn’t work well. In response to the president’s suggestion (explosion), the Navy did what the rest of Washington has done: blame Trump’s ignorance, e.g. here, in the Navy Times. Still, for what it’s worth, I think Trump’s idea has merit, especially if I can modify it a bit to suggest high pressure air (pneumatics) instead of high pressure steam.


Tests of the navy EMALS, notice that some launches go further than others; the problem is electronics, supposedly.

If you want to launch a 50,000 lb jet fighter at 5 g acceleration, you need to apply 250,000 lbs of force uniformly throughout the launch. For pneumatics, all that takes is 250 psi steam or air, and a 1000 square inch piston, about 3 feet in diameter. This is a very modest pressure and a quite modest size piston. A 50,000 lb object accelerated this way, will reach launch speed (130 mph) in 1.2 seconds. It’s very hard to get such fast or uniform acceleration with an electromagnetic coil since the motion of the coil always produces a back voltage. The electromagnetic pulses can be adjusted to counter this, but it’s not all that easy, as the Navy tests show. You have to know the speed and position of the airplane precisely to get it right, and have to adjust the firing of the pushing coils accordingly. There is no guarantee of smooth acceleration like you get with a piston, and the EMALS control circuit will always be vulnerable to electromagnetic and cyber attack. As things stand, the control system is thought to be the problem.

A piston is invulnerable to EM and cyber attack since, if worse comes to worse, the valves can be operated manually, as was done with steam-catapults throughout WWII. And pistons are very robust — far more robust than solenoid coils — because they are far less complex. As much force as you put on the plane, has to be put on the coil or piston. Thus, for 5 g acceleration, the coil or piston has to experience 250,000 lbs of horizontal force. That’s 3 million Newtons for those who like SI units (here’s a joke about SI units). A solid piston will have no problem withstanding 250,000 lbs for years. Piston steamships from the 50s are still in operation. Coils are far more delicate, and the life-span is likely to be short, at least for current designs. 

The reason I suggest compressed air, pneumatics, instead of steam is that air is not as hot and corrosive as steam. Also an air compressor can be located close to the flight deck, connected to the power center by electric wires. Steam requires long runs of steam pipes, a more difficult proposition. As a possible design, one could use a multi-stage, inter-cooled air compressor connected to a ballast tank, perhaps 5 feet in diameter x 100 feet long to guarantee uniform pressure. The ballast tank would provide the uniform pressure while allowing the use of a relatively small compressor, drawing less power than the EMALS. Those who’ve had freshman physics will be able to show that 5 g acceleration will get the plane to 130 mph in only 125 feet of runway. This is far less runway than the EMALS requires. For lighter planes or greater efficiency, one could shut off the input air before 120 feet and allow the remainder of the air to expand for 200 feet of the piston.

The same pistons could be used for capturing an airplane. It could start at 250 psi, dead-ended to the cylinder top. The captured airplane would push air back into the ballast tank, or the valve could be closed allowing pressure to build. Operated that way, the cylinder could stop the plane in 60 feet. You can’t do that with an EMAL. I should also mention that the efficiency of the piston catapult can be near 100%, but the efficiency of the EMALS will be near zero at the beginning of acceleration. Low efficiency at low speed is a problem found in all electromagnetic actuators: lots of electromagnetic power is needed to get things moving, but the output work,  ∫F dx, is near zero at low velocity. With EM, efficiency is high at only at one speed determined by the size of the moving coil; with pistons it’s high at all speeds. I suggest the Navy keep their EMALS, but only as a secondary system, perhaps used to launch drones until they get sea experience and demonstrate a real advantage over pneumatics.

Robert Buxbaum, May 19, 2017. The USS Princeton was the fanciest ship in the US fleet, with super high-tech cannons. When they mis-fired, it killed most of the cabinet of President Tyler. Slow and steady wins the arms race.

Nestle pays 1/4,000 what you pay for water

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When you turn on your tap or water your lawn, you are billed about 1.5¢ for every gallon of water you use. In south-east Michigan, this is water that comes from the Detroit river, chlorinated to remove bacteria, e.g. from sewage, and delivered to you by pipe. When Nestle’s Absopure division buys water, it pays about 1/4000 as much — $200/ year for 218 gallons per minute, and they get their water from a purer source, a pure glacial aquifer that has no sewage and needs no chlorine. They get a far better deal than you do, in part because they provide the pipes, but it’s mostly because they have the financial clout to negotiate the deal. They sell the Michigan water at an average price around $1/gallon, netting roughly $100,000,000 per year (gross). This allows them to buy politicians — something you and I can not afford.

Absopure advertises that I t will match case-for-case water donations to Flint. Isn't that white of them.

Absopure advertises that I t will match case-for-case water donations to Flint. That’s awfully white of them.

We in Michigan are among the better customers for the Absopure water. We like the flavor, and that it’s local. Several charities purchase it for the folks of nearby Flint because their water is near undrinkable, and because the Absopure folks have been matching the charitable purchases bottle-for bottle. It’s a good deal for Nestle, even at 50¢/gallon, but not so-much for us, and I think we should renegotiate to do better. Nestle has asked to double their pumping rate, so this might be a good time to ask to increase our payback per gallon. So far, our state legislators have neither said yes or no to the proposal to pump more, but are “researching the matter.” I take this to mean they’re asking Nestle for campaign donations — the time-honored Tammany method. Here’s a Detroit Free Press article.

I strongly suspect we should use this opportunity to raise the price by a factor of 400 to 4000, to 0.15¢ to 1.5¢ per gallon, and I would like to require Absopure to supply a free 1 million gallons per year. We’d raise $300,000 to $3,000,000 per year and the folks of Flint would have clean water (some other cities need too). And Nestle’s Absopure would still make $200,000,000 off of Michigan’s, clean, glacial water.

Robert Buxbaum, May 15, 2017. I ran for water commissioner, 2016, and have occasionally blogged about water, E.g. fluoridation, hidden rivers, and how you would drain a swamp, literally.

May 1, St. Tammany day

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May 1 is St. Tammany day, a day to rejoice in the achievements of Tammany Hall, and of St Tammany, the guardian of crooked politicians everywhere. The Sons of St. Tammany started in 1773 as a charitable club of notable revolutionary-era individuals including Benjamin Franklin, John Hancock, and John Dickenson, but evolved into perhaps the most corrupt, and American, of political organizations. The picture of a US politician – the cartoon version at least — is the Tammany Democrat: a loud, drunken, womanizer, willing to do or promise whatever the people seem to want at the moment. Tammany and its bosses helped form this image. They helped new immigrants, but did so by creating needless government jobs, by filling them often with incompetent loyalists, and by overcharging on government contracts. Today, these Tammany ways rule in every major American city; the other clubs of the day are gone or influence-less.

John Hancock leads a meeting of the St. Tammany (Columbian) society. Note the "Appeal to Heaven flag and the Indian, real or imagined. Indians participated in several, early St. Tammany meetings.

John Hancock leads a meeting of the St. Tammany society. Note the “Appeal to Heaven” flag. While Indians participated in some, early meetings, the one here is, I suspect, a ghost: St. Tammany.

In revolutionary-era America, the Sons of St. Tammany was just one of many social-charitable clubs (Americans like to form clubs), in many ways it was similar to the Masons and the Cincinnati, but those clubs were international and elitist. The sons of Tammany was purely American, and anti-elitist. It was open to anyone born on this side of the Atlantic, and had Indian customs. The Cincinnati society, for comparison, started with members who were as notable (Alexander Hamilton, George Washington, Marie, Marquis de Lafayette, Henry Knox, etc.) but was originally open only to high officers of the regular army, including foreigners like Lafayette, but not ordinary soldiers, minutemen (militia), or the general public. The symbols of the Tammanies were American: the liberty-cap and the “Appeal to Heaven” flag, now a popular symbol of the Tea Party; the leader was called by an Indian name: Sachem. By contrast, the Cincinnati society symbol was the Imperial Eagle (Washington’s was gold with diamonds), and the leader was called “general”. The Tammany society began admitting immigrants in 1810 or so, while the Cincinnati society remains closed to this day, except to descendants of Revolutionary officers — an aristocratic affectation in the eyes of some.

It was Aaron Burr who first saw the opportunity to use the Tammany organization as a for-profit, political machine. In the years 1795-9, New York was suffering from yellow fever and a variety of other diseases that were taken to be caused by a lack of clean water. Burr proposed, with Tammany support, the creation of a corporation to build a new water system to bring fresh, clean water from the Bronx River to lower Manhattan via iron pipes. The Manhattan company was duly chartered, with directors who were primarily Tammany men, Republican-Democrats, and not Federalists. Federalists (Hamilton, primarily) controlled the only NY banks at the time and controlled the directorate of every chartered company in the city. The Manhattan company requested a $2,000,000 perpetual charter, twice as big as the charter of Hamilton’s Bank of New York, and a monopoly on water distribution. These were reasonable requests given the task, but unusual in the lack of Federalist or governmental oversight. But the Manhattan company was a water company, and water was needed. But Burr’s intent, all along, it seems was to build a bank, not a water company. After the charter was approved, but before signing, he amended it to allow any excess funds to be used for any legal purpose. 

In this cartoon by Dr. Seuss, The Tammany Tiger says, "Today is the Big Day Folks. Vote Early and Often."

In this cartoon by Dr. Seuss, The Tammany Tiger says, “Today is the Big Day Folks. Vote Early and Often.”

Money was raised, but only $100,000 used for the water system. The remaining 95% of the charter funds, $1,900,000, went to found “The Bank of The Manhattan company” — later to be known as “The Chase Manhattan Bank” or “The Manhattan Bank of Cholera.” Instead of building the reservoir in upper Manhattan and filling it with clean water as originally proposed, Burr’s Tammany trustees voted to dig wells in lower Manhattan, and placed its reservoir in lower Manhattan too, near Chamber’s St,  next to a cemetery where Cholera victims were buried. New York suffered with Cholera, Typhoid, and leaky, wooden pipes until 1842 when Peter Cooper brought clean water to lower Manhattan from the Groton River via iron pipes. To this day, crooked water contracts are a staple of Tammany politics. 

The Bank of the Manhattan company opened at 40 Wall St on September 1, 1799, a mere four months after the water company’s incorporation. Hamilton was furious. The company continues today as The JP Morgan, Chase Manhattan Bank, one of the largest banking institutions in the world. Burr used the money and power of his company to reward supporters and to run for vice president with Thomas Jefferson’s tacit support. Except for his Tammany candidacy, John Adams would have won New York and a second term as president. Burr’s career pretty-well died after the Hamilton duel, but Tammany did well without him. By 1812, the Society built its first Tammany Hall, officially called the Wigwam, a $55,000, five-story building with a meeting hall for 2000. New York Democratic politics would center on Tammany Hall for the next century at least.

Following disappointment with John Quincy Adams, “the bitter branch of the bitter tree,” Tammy leaders went national. They recruited Andrew Jackson, a war hero and early recruit of Burr’s. They’d support Jackson if he’d hand over spoils, control of government jobs. He agreed and, as president, fired perfectly good, long-standing government employees He replaced them with Democratic loyalists. When Jackson stepped down in 1833, Tammany elected an equally corrupt New Yorker, Martin van Buren. Though there were periodic Whig and Republican reforms, Tammany learned they could wait those out. They always re-emerged like mushrooms after a rain.

Boss Tweed and other Tammany leaders: who stole the money?

Boss Tweed and other Tammany leaders in a cartoon by Nast, Tammany Ring. “Who stole the money? He did.”  

A key vote-getter in the Tammany system is to provide Thanksgiving dinners and other charitable giveaways for the poor, as well as promises of jobs. By the late 1800s, William J. Brian added promises of soft money and wealth redistribution, cornerstones of the Democratic platform to this day. Tammany also tends to be for low tariffs as opposed to the high tariff ideas of Hamilton and many Whigs and 19th century Republicans. A case can be made for either view.

Tammany helped New York immigrants, particularly the Irish to get citizenship and avoid legal troubles in return for votes and occasional muscle. In other cities, Democratic clubs were less open to Catholics, reflecting the views of the common voter in each state. In the North they were pro-union, in the South anti, electing Klu Kluxers like George Wallace, Sam Ervin, and Robert Byrd. This lead to a famous split in the Democratic party about the 1968 convention. Famous Tammany leaders include William M. “Boss” Tweed, “Big” Tim Sullivan, and “Gentleman” Jimmy Walker. Sullivan famously authored the first anti-gun law, the Sullivan act; it was designed to protect his thugs against private citizens shooting them. It didn’t always work.

Edwin Edwards, Democratic Governor of Louisiana. 1972-1996. Who would not trust this man?

Hon. (?) Edwin Edwards, Governor of Louisiana. 1972-1996. Tammany lives

If you want to see Tammany politics in action, visit almost any large US city, or read its newspaper. In Chicago, the dead vote, and 4 of the last 6 governors have gone to jail. Mayor Daily famously told Kennedy that 90 percent of the registered voters of Cook County would vote for him. They did (sort of); because of this, JFK won Illinois and the presidency. In New York, voters discovered only in the 1960s that Tammany’s leader, Carmine DeSapio had been working for 30 years with known gangland murderer, Charles “Lucky” Luciano. In Detroit, where I live and corruption in the water department is legendary. Race-based job handouts, unemployment is high along with high minimum (living) wages. We’re now in the process of a $70,000,000 project to replace 100 feet of sewer pipe, and we’re building a $140 million, 3.3 mile trolley. Tammany loves all public works.

Then there is Louisiana, home to St Tammany parish. Louisiana Democrats like Huey Long and Edwin Edwards (shown at left) are unusual in that they’re proud to say that their corrupt methods are corrupt. Edwards has had two long runs as governor despite several convictions for doing illegal things he admits to doing. When Edwards was asked why he did favors for his friends. He responded: “Who should I do them for? My enemies?” Or, to quote one of Edwin Edwards campaign ads. Vote Edwin EdwardsPeople seem to love it, or did until the levy broke. There is a particularly American grandeur to all this. As Will Rodgers said, “America has the best politicians money can buy.” Today is the day to be proud of that uniquely American tradition. You too can grow up to buy a president.

Robert Buxbaum, April 28, 2017. I ran for water commissioner, and have written about sewage treatment, flood avoidance, and fluoride, as well as the plusses and minuses of trade unionization, and the difference between Republicans and Conservatives.

pee in the shower and other water savers

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Do you want to save the planet and save money at the same time? Here are some simple tips:

The first money and planet saver, is to pee in the shower. For those who don’t have a lawn, or who don’t water, your single biggest water cost is likely the toilet. Each person in your household will use it several times per day, at roughly 1.6 gallons per flush. In Oak Park, Michigan the cost of water is 1.5¢/gallon, so each flush costs you, roughly 2.5¢. If you pee in the shower every morning, you’ll save yourself about one flush per day, or 2.5¢. Over the course of a year you’ll have used about 500 gallons less, and will have saved yourself somewhere between $5 and $10. Feel good about yourself every morning; the effort involved is truly minimal.

Related to peeing in the shower, I should mention that many toilets leak. A significant part of your water bill can often be cut by replacing the “flapper valve on the inside of your toilet tank, and/or by cleaning the needle fill valve. To see if you need this sort of help, put a few drops of food dye in the toilet when you leave in the morning. If the color is largely gone by the time you get back, the toilet is leaking the equivalent of a few volumes per day, that is at least as much water as is flushed. If the color goes faster, or you hear the tank refill when no one used it, you’re leaking more. Check the flapper and replace it if it’s worn — it’ll cost about $3 — and check the needle-fill valve. They don’t work forever. Cleanliness is near godliness.

Mulch is good, this is too much concentrated by the tree trunk. Use only 2 inches and spread it out to save water and weeding.

Mulch is good, this is too much concentrated by the tree trunk. Use only 2-3 inches and spread it out from the trunk to save water and weeding without attracting bugs.

If your valve is leaking and you decide to replace it, you may want to replace with a variable flush valve. Typically, there are two options: a big vale for big flush (1.6 gal) and a small valve for small flush (1 gal or less). These are widely used in Europe. You can make up for this cost rather quickly at 1.5¢/gallon.

The next big issue is lawn-care. If you water your lawn and flowers daily, you’ve likely noticed that you pay about $300/month for water in the summer: a lot more than in the winter, or than your lazes-faire neighbor in the summer. Every $150 of summer-excess, water bill you pay represents about 10,000 gallons applied to your lawn. That’s a cubic foot, or 1¢ to 2¢ of water applied per ft2 per month for typical watering. While many sites advise that you can save by adding a rain barrel, I disagree. Rain barrels are costly, ugly, and are a lot of work ago plumb in. And each barrel only holds 55 gallons of water, 82¢ worth when full. You do a lot better, IMHO by putting down an inch or two of mulch around your flowers and vegetables. This mulch requires no work and will keep you from needing to water these areas for the 3-4 days after every rainfall. A layer of 1″ to 2″ will help your soil hold 0.5 to 1 gallon of water per square foot. At typical prices of mulch and water, this will pay for itself in 1-2 years and will help you avoid weeding. Mulch is a far better return than the rain-barrels that are often touted, and there’s far less effort involved. Buy the mulch, not the barrel, but don’t put down too more than 2″ on flowers and vegetable. Trees can take 3 -4″; don’t use more. Avoid a mulch mountain right next to a tree, it causes the roots to grow weird, and provides a home for bugs and undesirable anaerobic molds.

A little more work than the above is to add a complete rain garden or bioswale. Build it at the bottom of any large incline on your property, where the water runs off (It’s likely a soggy swamp already). Dig the area deeper and put, at the bottom of the hole, a several-inch layer of mulch and gravel. Top it off with the soil you just removed, ideally raising the top high enough that, if the rain garden should fill, the water will run off to the street. Plant in the soil at the top long-rooted grasses, or flowers, vegetables, or water-tolerant trees. You may want to direct the water from your home’s sump pump here too (It can help to put a porous pipe at the bottom to distribute this water). If you do this right, you’ll get vegetables or trees and you won’t have to water the garden, ever. Also, you’ll add value to your property by removing the swampy eyesore. You’ll protect your home too, since a major part of home flooding comes from the water surge of sump water to the sanitary sewer.

Robert E. Buxbaum, April 14, 2017. I ran for water commissioner, Oakland County, MI, Nov. 2016. Among my other thoughts: increased retention to avoid flooding, daylighting rivers, and separating the sanitary from the storm sewers. As things stand, the best way to save money on water– get the same deal the state gave to Nestle/ Absopure: they pay only $200/year to pump 200 gal/minute. That is, they pay only 1/3000 of what you and I pay. It helps to have friends in government.

The hydrogen jerrycan

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Here’s a simple invention, one I’ve worked on off-and-on for years, but never quite built. I plan to work on it more this summer, and may finally build a prototype: it’s a hydrogen Jerry can. The need to me is terrifically obvious, but the product does not exist yet.

To get a view of the need, imagine that it’s 5-10 years in the future and you own a hydrogen, fuel cell car. You’ve run out of gas on a road somewhere, per haps a mile or two from the nearest filling station, perhaps more. You make a call to the AAA road-side service and they show up with enough hydrogen to get you to the next filling station. Tell me, how much hydrogen did they bring? 1 kg, 2 kg, 5 kg? What did the container look like? Is there one like it in your garage?

The original, German "Jerry" can. It was designed at the beginning of WWII to help the Germans to overrun Europe.

The original, German “Jerry” can. It was designed at the beginning of WWII to help the Germans to overrun Europe. I imagine the hydrogen version will be red and roughly these dimensions, though not quite this shape.

I figure that, in 5-10 years these hydrogen containers will be so common that everyone with a fuel cell car will have one, somewhere. I’m pretty confident too that hydrogen cars are coming soon. Hydrogen is not a total replacement for gasoline, but hydrogen energy provides big advantages in combination with batteries. It really adds to automotive range at minimal cost. Perhaps, of course this is wishful thinking as my company makes hydrogen generators. Still it seems worthwhile to design this important component of the hydrogen economy.

I have a mental picture of what the hydrogen delivery container might look like based on the “Jerry can” that the Germans (Jerrys) developed to hold gasoline –part of their planning for WWII. The story of our reverse engineering of it is worth reading. While the original can was green for camouflage, modern versions are red to indicate flammable, and I imagine the hydrogen Jerry will be red too. It must be reasonably cheap, but not too cheap, as safety will be a key issue. A can that costs $100 or so does not seem excessive. I imagine the hydrogen Jerry can will be roughly rectangular like the original so it doesn’t roll about in the trunk of a car, and so you can stack a few in your garage, or carry them conveniently. Some folks will want to carry an extra supply if they go on a long camping trip. As high-pressure tanks are cylindrical, I imagine the hydrogen-jerry to be composed of two cylinders, 6 1/2″ in diameter about. To make the rectangular shape, I imagine the cylinders attached like the double pack of a scuba diver. To match the dimensions of the original, the cylinders will be 14″ to 20″ tall.

I imagine that the hydrogen Jerry can will have at least two spouts. One spout so it can be filled from a standard hydrogen dispenser, and one so it can be used to fill your car. I suspect there may be an over-pressure relief port as well, for safety. The can can’t be too heavy, no more than 33 lbs, 15 kg when full so one person can handle it. To keep the cost and weight down, I imagine the product will be made of marangeing steel wrapped in kevlar or carbon fiber. A 20 kg container made of these materials will hold 1.5 to 2 kg of hydrogen, the equivalent of 2 gallons of gasoline.

I imagine that the can will have at least one handle, likely two. The original can had three handles, but this seems excessive to me. The connection tube between two short cylinders could be designed to serve as one of the handles. For safety, the Jerrycan should have a secure over-seal on both of the fill-ports, ideally with a safety pin latch minimize trouble in a crash. All the parts, including the over- seal and pin, should be attached to the can so that they are not easily lost. Do you agree? What else, if anything, do you imagine?

Robert Buxbaum, February 26, 2017. My company, REB Research, makes hydrogen generators and purifiers.

A very clever hydrogen pump

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I’d like to describe a most clever hydrogen pump. I didn’t invent it, but it’s awfully cool. I did try to buy one from “H2 Pump,” a company that is now defunct, and I tried to make one. Perhaps I’ll try again. Here is a diagram.

Electrolytic membrane H2 pump

Electrolytic membrane H2 pump

This pump works as the reverse of of a PEM fuel cell. Hydrogen gas is on both sides of a platinum-coated, proton-conducting membrane — a fuel cell membrane. As in a PEM fuel cell, the platinum splits the hydrogen molecules into H atoms. An electrode removes electrons to form H+ ions on one side of the membrane; the electrons are on the other side of the membrane (the membrane itself is chosen to not conduct electricity). The difference from the fuel cell is that, for the pump you apply a energy (voltage) to drive hydrogen across the membrane, to a higher pressure side; in a fuel cell, the hydrogen goes on its own to form water, and you extract electric energy.

As shown, the design is amazingly simple and efficient. There are no moving parts except for the hydrogen itself. Not only do you pump hydrogen, but you can purify it as well, as most impurities (nitrogen, CO2) will not go through the membrane. Water does permeate the membrane, but for many applications, this isn’t a major impurity. The amount of hydrogen transferred per plate, per Amp-second of current is given by Faraday’s law, an equation that also shows up in my discussion of electrolysis, and of electroplating,

C= zFn.

Here, C is the current in Amp-seconds, z is the number or electrons transferred per molecule, in this case 2, F is Faraday’s constant, 96,800, n is the number of mols transferred.  If only one plate is used, you need 96,800 Amp-seconds per gram of hydrogen, 53.8 Amp hours per mol. Most membranes can operate at well at 1.5 Amp per cm2, suggesting that a 1.1 square-foot membrane (1000 cm2) will move about 1 mol per minute, 22.4 slpm. To reduce the current requirement, though not the membrane area requirement, one typically stacks the membranes. A 100 membrane stack would take 16.1 Amps to pump 22.4 slpm — a very manageable current.

The amount of energy needed per mol is related to the pressure difference via the difference in Gibbs energy, ∆G, at the relevant temperature.

Energy needed per mol is, ideally = ∆G = RT ln Pu/Pd.

where R is the gas constant, 8.34 Joules per mol, T is the absolute temperature, Kelvins (298 for a room temperature process), ln is the natural log, and Pu/Pd is the ratio of the upstream and downstream pressure. We find that, to compress 2 grams of hydrogen (one mol or 22.4 liters) to 100 atm (1500 psi) from 1 atm you need only 11400 Watt seconds of energy (8.34 x 298 x 4.61= 11,400). This is .00317 kW-hrs. This energy costs only 0.03¢ at current electric prices, by far the cheapest power requirement to pump this much hydrogen that I know of. The pump is surprisingly compact and simple, and you get purification of the hydrogen too. What could possibly go wrong? How could the H2 pump company fail?

One thing that I noticed went wrong when I tried building one of these was leakage at the seals. I found it uncommonly hard to make seals that held even 20 psi. I was using 4″ x 4″ membranes so 20 psi was the equivalent of 320 pounds of force. If I were to get 200 psi, there would have been 3200 lbs of force. I could never get the seals to stay put at anything more than 20 psi.

Another problem was the membranes themselves. The membranes I bought were not very strong. I used a wire-mesh backing, and a layer of steel behind that. I figured I could reach maybe 200 psi with this design, but didn’t get there. These low pressures limit the range of pump applications. For many applications,  you’d want 150-200 psi. Still, it’s an awfully cool pump,

Robert E. Buxbaum, February 17, 2017. My company, REB Research, makes hydrogen generators and purifiers. I’ve previously pointed out that hydrogen fuel cell cars have some dramatic advantages over pure battery cars.

Rethinking fluoride in drinking water

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Fluoride is a poison, toxic tor a small child in doses of 500 mg, and toxic to an adult in doses of a few thousand mg. It is a commonly used rat poison that kills by robbing the brain of the ability to absorb oxygen. In the form of hydrofluoric acid, it is responsible for the deaths of more famous chemists than any other single compound: Humphrey Davy died trying to isolate fluorine; Paul Louyet and Jerome Nickles, too. Thomas Knox nearly died, and Henri Moissan’s life was shortened. Louis-Joseph Gay Lussac, George Knox, and Louis- Jacques Thenard suffered burns and similar, George Knox was bedridden for three years. Among the symptoms of fluoride poisoning is severe joint pain and that your brain turns blue.

In low doses, though, fluoride is thought to be safe and beneficial. This is a phenomenon known as hormesis. Many things that are toxic at high doses are beneficial at low. Most drugs fall into this category, and chemotherapy works this way. Diseased cells are usually less-heartythan healthy ones. Fluoride is associated with strong teeth, and few cavities. It is found at ppm levels many well water systems, and has shown no sign of toxicity, either for humans or animals at these ppm levels. Following guidelines set by the AMA, we’ve been putting fluoride in drinking water since the 1960s at concentrations between 0.7 and 1.2 ppm. We have seen no deaths or clear evidence of any injury from this, but there has been controversy. Much of the controversy stems from a Chinese study that links fluoride to diminished brain function, and passivity (Anti-fluoriders falsely attribute this finding to a Harvard researcher, but the Harvard study merely cites the Chinese). The American dental association strongly maintains that worries based on this study are groundless, and that the advantage in lower cavities more than off-sets any other risks. Notwithstanding, I thought I’d take another look. The typical US adult consumes 1-3 mg/day the result of drinking 1-3 liters of fluoridated water (1 ppm = 1 mg/liter). This < 1/1000 the toxic dose,

While there is no evidence that people who drink high-fluoride well water are any less-healthy than those who drink city water, or distilled / filtered water, that does not mean that our city levels are ideal. Two months ago, while running for water commissioner, I was asked about fluoride, and said I would look into it. Things have changed since the 1960s: our nutrition has changed, we have vitamin D milk, and our toothpastes now contain fluoride. My sense is we can reduce the water concentration. One indication that this concentration could be reduced is shown below. Many industrial countries that don’t add fluoride have similar tooth decay rates to the US.

World Health Organization data on tooth decay and fluoridation.

World Health Organization data on tooth decay and fluoridation.

This chart should not be read to suggest that fluoride doesn’t help; all the countries shown use fluoride toothpaste, and some give out fluoride pills, too. And some countries that don’t add fluoride have higher levels of cavities. Norway and Japan, for example, don’t add fluoride and have 50% more cavities than we do. Germany doesn’t add fluoride, and has fewer cavities, but they hand out fluoride pills, To me, the chart suggests that our levels should go down, though not to zero. In 2015, the Department of Health recommend lowering the fluoride level to 0.7 ppm, the lower end of the previous range, but my sense from the experience of Europe is that we should go lower still. If I were to pick, I’d choose 1/2 the original dose: 0.6 to 0.35 ppm. I’d then revisit in another 15 years.

Having picked my target fluoride concentration, I checked to see the levels in use in Oakland county, MI, the county I was running in. I was happy to discover that most of the water the county drinks, that provided by Detroit Water and Sewage, NOCWA and SOCWA already have decreased levels of 0.43-0.55 ppm. These are just in the range I would have picked, Fluoride concentrations are higher in towns that use well water, about  0.65-0.85 ppm. I do not know if this is because the well water comes from the ground with these fluoride concentrations or if the towns add, aiming at the Department of Health target. In either case, I don’t find these levels alarming. If you live none of these town, or outside of Oakland county, check your fluoride levels. If they seem high, write to your water commissioner. You can also try switching from fluoride toothpaste to non-fluoride, or baking soda. In any case, remember to brush. That does make a difference, and it’s completely non-toxic.

Robert Buxbaum, January 9, 2017. I discuss chloride addition a bit in this essay. As a side issue, a main mechanism of sewer pipe decay seems related to tooth decay. That is the roofs of pipe attract acid-producing, cavity causing bacteria that live off of the foul sewer gas. The remedies for pipe erosion include cleaning your pipes regularly, having them checked by a professional once per year, and repairing cavities early. Here too, it seems high fluoride cement resists cavities better.

A British tradition of inefficiency and silliness

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While many British industries are forward thinking and reasonably efficient, i find Britons take particular pride in traditional craftsmanship. That is, while the Swiss seem to take no particular pride in their coo-coo clocks, the British positively glory in their handmade products: hand-woven, tweed jackets, expensive suits, expensive whiskey, and hand-cut diamonds. To me, an American-trained engineer, “traditional craftsmanship,” of this sort is another way of saying silly and in-efficient. Not having a better explanation, I associate these behaviors with the decline of English power in the 20th century. England went from financial and military preëminence in 1900 to second-tier status a century later. It’s an amazing change that I credit to tradition-bound inefficiency — and socialism.

Queen Elizabeth and Edward VII give the Nazi solute.

Queen Elizabeth and Edward VII give the Nazi solute.

Britain is one of only two major industrial nations to have a monarch and the only one where the monarch is an actual ambassador. The British Monarchy is not all bad, but it’s certainly inefficient. Britain benefits from the major royals, the Queen and crown prince in terms of tourism and good will. In this she’s rather like our Mickey Mouse or Disneyland. The problem for England has to do with the other royals, We don’t spend anything on Mickey’s second cousins or grandchildren. And we don’t elevate Micky’s relatives to military or political prominence. England’s royal leaders gave it horrors like the charge of the light brigade in the Crimean war (and the Crimean war itself), Natzi-ism doing WWII, the Grand Panjandrum in WWII, and the attack on Bunker Hill. There is a silliness to its imperialism via a Busby-hatted military. Britain’s powdered-wigged jurors are equally silly.

Per hour worker productivity in the industrial world.

Per hour worker productivity in the industrial world.

As the chart shows, England has the second lowest per-hour productivity of the industrial world. Japan, the other industrial giant with a monarch, has the lowest. They do far better per worker-year because they work an ungodly number of hours per year. French and German workers produce 20+% more per hour: enough that they can take off a month each year and still do as well. Much of the productivity advantage of France, Germany, and the US derive from manufacturing and management flexibility. US Management does not favor as narrow a gene pool. Our workers are allowed real input into equipment and product decisions, and are given a real chance to move up. The result is new products, efficient manufacture, and less class-struggle.

The upside of British manufacturing tradition is the historical cachet of English products. Americans and Germans have been willing to pay more for the historical patina of British whiskey, suits, and cars. Products benefit from historical connection. British suits remind one of the king, or of James Bond; British cars maintain a certain style, avoiding fads of the era: fins on cars, or cup-holders, and electric accessories. A lack of change produces a lack of flaws too, perhaps the main things keeping Britain from declining faster. A lack of flaws is particularly worthwhile in some industries, like banking and diamonds, products that have provided an increasing share of Britain’s foreign exchange. The down-side is a non-competitive military, a horrible food industry, and an economy that depends, increasingly on oil.

Britain has a low birthrate too, due in part to low social mobility, I suspect. Social mobility looked like it would get worse when Britain joined the European Union. An influx of foreign workers entered taking key jobs including those that with historical cachet. The Brits reacted by voting to leave the EC, a vote that seems to have taken the upper class by surprise, With Brexit, we can hope to see many years more of manufacturing by the traditional and silly.

Robert Buxbaum, December 31, 2016. I’ve also written about art, good and bad, about the US aesthetic of strength, about the French tradition of innovation, And about European vs US education.