REB Research periodic table cup

Some 20 years ago I designed this periodic table cup, but with only the 103 named elements that existed then. In part this was done because I wanted a good, large, white coffee cup, in part because I often found I needed a periodic table, and didn’t like to have to look one up, and in part to people how much more area you get on a cylinder than on a flat sheet (roughly 3.14 times more area). To show that, I put all the side elements (rare earth lanthanides, and actinides) where they belonged, and not off on the side. I also put hydrogen in twice, once as a metal (HCl) and once as a non metal (NaH). The color I chose was Tryian Blue, a key color of Biblical Tyre, what you get from male purpura mollusks (the females give a shade of red that I also try to associate with REB Research).

I’ve updated the cup to add more elements: I think it’s great. You can buy it for $30 through our web-site, or for $25 by e-mailing me (reb@rebresearch.com). Or if you do something really cool, I may send you one for free.

REB Research, Periodic table coffee cup

REB Research, Periodic table coffee cup

By the way, I only use 4 digits for the atomic weight; I can think of no application where a normal person needs more.

 

 

Theodore Roosevelt jumps fence, rides moose

One of my favorite presidents, a liberal Republican, a friend to immigrants and  the poor, but not opposed to prosperity either. Though some thought he might be crazy, none thought he was a wuss, and none messed with him or the USA when he was in office. Yes, that’s the president riding a moose, jumping a fence, and camping on a cliff with John Muir.

theodore-roosevelt-mooseTheodore Roosevelt Jumps Fence on Horsetheodore-roosevelt-yosemite

 

January 16, 2013 R.E. Buxbaum. If you liked this, you might want my insights into a famous incident where Teddy Roosevelt got shot on the way to giving a speech. Instead of treatment, he gave the 2 hour speech and survived. Why did he do this? How did he survive it?

How hydrogen and/or water can improve automobile mileage (mpg)

In case you’ve ever wondered why it was that performance cars got such poor milage, or why you got such bad milage in the city, the biggest single problem has to do with the vacuum drawn by the engine, some of the problem has to do with the speed of combustion, some has to do with rolling friction, and some with start/stop loss too. Only a very small fraction of the energy is lost on air friction until you reach highway speeds.

Lets consider vacuum loss first as it is likely the worst offender. A typical US car, e.g. a Chevy Malibu, has a 3.5 liter engine (a performance car has an engine that’s much larger). As you toodle down a street at 35 mph, your engine is going at about 2000 rpm, or 33 rps. Since the power required to move the car is far less than the 200 hp that the car could deliver, the air intake is throttled so that the engine is sucking a vacuum of about 75 kpa (10 psi for those using English units). To calculate the power loss this entails, multiply 33*3.5*80; this is about 8662 Watts, or 12 hp. To find the energy use per mile, divide by your average speed, 25 mph (it would be 35 mph, but you sometimes stop for lights). 8 kW/25 mph = .21 kW-hr/mile. One finds, as I’ll show that the car expends more energy sucking this vacuum than pushing the car itself. This is where the majority of the city mpg goes in a normal car, but it’s worse in a high performance car is worse since the engine is bigger. In city driving, the performance mpg will be lower than for a Malibu even if the performance car is lighter, if it has better aerodynamics (it does), and if you never stop at lights.

The two other big places were city mileage goes is overcoming rolling friction and the need to stop and go at lights, stop signs, etc. The energy used for rolling friction is the force it would take to push your car on level ground when in neutral times the distance. For a typical car, the push force is about 70 lbs or 32 kgs or 315 Nt; it’s roughly proportional to the car’s weight. At 35 mph, or 15.5 m/s, the amount of power this absorbs is calculated as the product of force and speed: 15.5*315 = 4882 W, or about 6.5 hp. The energy use is 4.9 kW/35 mph =.14 kWhr/mile. The energy loss from stop lights is similar to this, about .16 kWhr/mile, something you can tell by getting the car up to speed and seeing how far it goes before it stops. It’ll go about 2-3 blocks, a little less distance than you are likely to go without having to stop. Air resistance adds a very small amount at these speeds, about 2000 W, 2.7 hp, or .05 kWhr/mile; it’s far more relevant at 65 mph, but still isn’t that large.

If you add all this together, you find the average car uses about .56 kWhr/mile. For an average density gasoline of 5.6 lb/gal, and average energy-dense gasoline, 18,000 BTU/lb, and an average car engine efficiency of 11000 BTU/kWhr, you can now predict an average city gas mileage of 16.9 mpg, about what you find experimentally. Applying the same methods to highway traffic at 65 mph, you predict .38 kWhr/mile, or 25 mpg. Your rpms are the same on the highway as in the city, but the throttle is open so you get more power and loose less to vacuum.

Now, how do you increase a car’s mpg. If you’re a Detroit automaker you could reduce the weight of the car, or you the customer can clean the junk out of your trunk. Every 35 lbs or so increases the rolling friction by about 1%. These is another way to reduce rolling friction and that’s to get low resistance tires, or keep the tires you’ve got full of air. Still, what you’d really like to do is reduce the loss to vacuum energy, since vacuum loss is a bigger drain on mpg.

The first, simple way to reduce vacuum energy loss is to run lean: that is, to add more air than necessary for combustion. Sorry to say, that’s illegal now, but in the olden days before pollution control you could boost your mpg by adjusting your carburator to add about 10% excess of air. This reduced your passing power and the air pollution folks made it illegal (and difficult) after they noticed that it excess air increased NOx emissions. The oxygen sensor on most cars keeps you from playing with the carburator these days.

Another approach is to use a much smaller engine. The Japanese and Koreans used to do this, and they got good milage as a result. The problem here is that you now had to have a very light car or you’d get very low power and low acceleration — and no American likes that. A recent approach to make up for some of the loss of acceleration is by adding a battery and an electric motor; you’re now making a hybrid car. But the batteries add significant cost, weight and complexity to these cars, and not everyone feels this is worth it. So now on to my main topic: adding steam or hydrogen.

There is plenty of excess heat on the car manifold. A simile use of this heat is to warm some water to the point where the vapor pressure is, for example, 50 kPa. The pressure from this water adds to the power of your engine by allowing a reduction in the vacuum to 50 kPa or less. This cuts the vacuum loss at low speeds. At high speed and power the car automatically increases the air pressure and the water stops evaporating, so there is no loss of power. I’m currently testing this modification on my own automobile partly for the fun of it, and partly as a preface to my next step: using the car engine heat to run the reaction CH3OH + H2O –> CO2 + H2. I’ll talk more about our efforts adding hydrogen elsewhere, but thought you might be interested in these fundamentals.

http://www.rebresearch.com

Link

Here’s a murder map showing Detroit’s 387 homicides in 2012, plus the homicides in the surrounding areas. Courtesy of the Detroit Free Press. It shows you where the murder took place; click on the dot, and you’ll  get more details: dates, weapons, etc. 

Here is an updated map for 2014 + half of 2015. The link has some details of the various crimes, but less than before. Detroit has not gotten measurably safer.

Murder map for 2014 (orange dots) and Jan to june 29 2015 (grey dots) From here

How and why membrane reactors work

Here is a link to a 3 year old essay of mine about how membrane reactors work and how you can use them to get past the normal limits of thermodynamics. The words are good, as is the example application, but I think I can write a shorter version now. Also, sorry to say, when I wrote the essay I was just beginning to make membrane reactors; my designs have gotten simpler since.

At left, for example, is a more modern, high pressure membrane reactor design. A common size is  72 tube reactor assembly; high pressure. The area around the shell is used for heat transfer. Normally the reactor would sit with this end up, and the tube area filled or half-filled with catalyst, e.g. for the water gas shift reaction, CO + H2O –> CO2 + H2 or for the methanol reforming CH3OH + H2O –> 3H2 + CO2, or ammonia cracking 2NH3 –> N2 + 3H2. According to normal thermodynamics, the extent of reaction for these reactions will be negatively affected by pressure (WGS is unaffected). Separation of the hydrogen generally requires high pressure and a separate step or two. This setup combines the steps of reaction with separation, give you ultra high purity, and avoids the normal limitations of thermodynamics.

Once equilibrium is reached in a normal reactor, your only option to drive the reaction isby adjusting the temperature. For the WGS, you have to operate at low temperatures, 250- 300 °C, if you want high conversion, and you have to cool externally to remove the heat of reaction. In a membrane reactor, you can operate in your preferred temperature ranges and you don’t have to work so hard to remove, or add heat. Typically with a MR, you want to operate at high reactor pressures, and you want to extract hydrogen at a lower pressure. The pressure difference between the reacting gas and the extracted hydrogen allows you to achieve high reaction extents (high conversions) at any temperature. The extent is higher because you are continuously removing product – H2 in this case.

Here’s where we sell membrane reactors; we also sell catalyst and tubes.

True (magnetic) north

Much of my wife’s family is Canadian, so I keep an uncommon interest in Canada — for an American. This is to say, I think about it once a month or so, more often during hockey season. So here is a semi-interesting factoid:

The magnetic north pole, the “true north” has been moving northwest for some time, but the rate has increased over the last few decades as the picture shows. It has now left the northern Canadian islands, so Canada is no longer “The true north, strong and free.” (It seems to be strong and free). True north  is now moving northwest, toward Siberia. true magnetic north heading to Russia

Healthcare thoughts

I offer healthcare to keep workers working for me — it’s an employee retention benefit that helps cover the cost of training. As it is now, if they quit, covered workers will have to pay for their own heathcare or find another company that’s willing to pay for it.

Perhaps that’s mean to think this way, but it’s really my only means to keep people from jumping shop at the first higher-paying opportunity. Anyway, that’s what I do/did. When congress gave free healthcare to everyone as of this year, they not only raised my taxes, and my company taxes, they also removed a key tool I have for keeping people on the job. In return, I suppose my healthcare fees are supposed to go down, but I have no faith they will, in part because I worked for the government and have no faith in their ability to be efficient or fast moving; in part because my ability to pay for healthcare comes from my ability to keep trained workers.

Though I’m not too happy about the change, I imagine (hope) that my employees are happy. Their  taxes will go up a bit, but they will be more free to jump ship at will. I imagine that the unemployed are especially thrilled, though I don’t know why that was not implemented through an increase in Medicare and Medicaid. In a sense I’m surprised it took congress this long to give everyone “free” healthcare without forcing them to work for it.

Creepy sculpture at REB Research & Consulting.

Me with Gilroy

Me with Gilroy

During our downtime, I’ve been making a creepy sculpture that I call Gilroy. It looks a lot like Kilroy of WW2 fame, but its eyes follow you through use of a reasonably clever optical illusion. I’ve embedded a video of my secretary, Libby, standing next to our current, small version of Gilroy (Gilroy is the less hairy one on the right). If the embedded video works, you’ll see Gilroy’s eyes follow you. My secretary, Libby (more hair) is on the left. Her eyes follow you too, but less creepily .Gilroy and CL Brodman – Wi-Fi
Here’s what we do more normally at REB Research (hydrogen purifiers and hydrogen generators).